Hi Harvey,
Thanks for your reply. Having looked at the manual, I cannot see that water can get anywhere near the carb. Although I couldn't smell it yesterday, I can now, and it smells like (very old) fuel - I had some 10 year old four-star that I added to the old four-star already in the tank earlier in the year. (Maybe that was a mistake!) The tube is next to the emissions control tube and looks to be a carb overflow pipe - it just goes to open air down the engine.
This morning the car won't start at all - it tries - with some fresh fuel in. I'll recharge the battery and see if things will happen! When it was running yesterday the engine was running very smoothly.
M