Those wheels look really nice! I want to see some pics on the car!
Before you put tyres on them, measure the actual offset. Ie measure the total width across the rim and divide by 2 to get the amount the wheel would stick out each side of the centre line for zero offset. Then measure from the hub mating face of the wheel out to the back rim. The difference is the offset - if the hub to rim is greater then the offset is into the car, hub to rim smaller the offset is out from the car - up to you which you call positive and which negative! Width of the rim is irrelevant to this calculation - you're just trying to measure how far the centre line of the rim is offset from the hub mating face (hence the term offset!)
My reckoning is that the ideal offset to allow the widest possible tyre at full rolling radius is 53mm into the car.
I got my handy tyre calculator out and 205/55 is virtually a perfect match on rolling diameter, 215/55 is plus 2%, 215/50 is minus 1%, 215/45 is minus 5%, 225/50 is spot on, 225/45 is minus 3%.
With 205/55 you would need the offset to be spot on not to have any clearance issues. Reducing the rolling diameter improves clearance at the expense of lowering overall gearing (it pulls the wide part of the tyre backwards away from the pinch point behind the D post), so if you were going to go for 215 then I'd be inclined to go for 215/45. I'm pretty sure you'd have no chance with 225's.
Important to try a scrap tyre first before committing too many pennies! And don't forget that with the de dion rear axle the rear track changes with supension compression - so try it slightly jacked up and then with a ton of lead in the boot! You never know, a get out of jail card might be new full ride height rear springs, or new lowered rear springs, depending which way you need to win clearance.
If the car is too thrashy afterwards you could always fit an LT77 (ex SD1) or R390 (later version of LT77 in Discoveries, Sherpa vans etc etc) 5 speed overdrive manual or ZF HP22 4 speed overdrive auto to bring the overall gearing back up.
Chris